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Recent advances of small-molecule fluorescent probes for detecting biological hydrogen sulfide

《化学科学与工程前沿（英文）》 2022年 第16卷 第1期   页码 34-63 doi: 10.1007/s11705-021-2050-1

摘要： H2S is well-known as a colorless, acidic gas, with a notoriously rotten-egg smell. It was recently revealed that H2S is also an endogenous signaling molecule that has important biological functions, however, most of its physiology and pathology remains elusive. Therefore, the enthusiasm for H2S research remains. Fluorescence imaging technology is an important tool for H2S biology research. The development of fluorescence imaging technology has realized the study of H2S in subcellular organelles, facilitated by the development of fluorescent probes. The probes reviewed in this paper were categorized according to their chemical mechanism of sensing and were divided into three groups: H2S reducibility-based probes, H2S nucleophilicity-based probes, and metal sulfide precipitation-based probes. The structure of the probes, their sensing mechanism, and imaging results have been discussed in detail. Moreover, we also introduced some probes for hydrogen polysulfides.

关键词： hydrogen sulfide     fluorescent probe     reducibility     nucleophilicity     copper sulfide precipitate     hydrogen polysulfides    

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Structural and optical properties of nanostructured copper sulfide semiconductor synthesized in an industrial

Marcela Achimovičová, Erika Dutková, Erika Tóthová, Zdenka Bujňáková, Jaroslav Briančin, Satoshi Kitazono

《化学科学与工程前沿（英文）》 2019年 第13卷 第1期   页码 164-170 doi: 10.1007/s11705-018-1755-2

摘要：

Chalcogenide nanostructured semiconductor, copper sulfide (CuS) was prepared from copper and sulfur powders in stoichiometric ratio by a simple, fast, and convenient one-step mechanochemical synthesis after 40 min of milling in an industrial eccentric vibratory mill. The kinetics of the mechanochemical synthesis and the influence of the physical properties of two Cu powder precursor types on the kinetics were studied. The crystal structure, physical properties, and morphology of the product were characterized by X-ray diffraction (XRD), the specific surface area measurements, particle size distribution and scanning electron microscopy. The XRD analysis confirmed the hexagonal crystal structure of the product-CuS (covellite) with the average size of the crystallites 11 nm. The scanning electron microscopy analysis has revealed that the agglomerated grains have a plate-like structure composed of CuS nanoparticles. The thermal analysis was performed to investigate the thermal stability of the mechanochemically synthesized CuS. The optical properties were studied using UV-Vis and photoluminescence spectroscopy. The determined optical band gap energy 1.80 eV responds to the value of the bulk CuS, because of agglomerated nanoparticles. In addition, a mechanism of CuS mechanochemical reaction was proposed, and the verification of CuS commercial production was performed.

关键词： copper sulfide     industrial mechanochemical synthesis     thermal analysis     optical properties    

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迎接铜工业挑战——低成本处理硫化铜精矿途径的思考

朱祖泽

《中国工程科学》 2000年 第2卷 第2期   页码 87-90

摘要：

对过去10年来铜冶炼的技术进步和铜价格的变化作出的简要回顾指出，未来铜市场的竞争是取决于冶炼技术的生产成本的竞争。坚持自我研究开发和引进相结合才能保证我国铜工业健康稳定发展，并能应付国际竞争。评述了现在强氧化-PS转炉吹炼-火法精炼-电解流程的不足；分析了火湿法联合流程的可能性及依据；新的火湿法联合流程将有更强的竞争优势。

关键词： 未来铜工业     硫化铜精矿     低成本处理    

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Silica-based nanoarchitecture for an optimal combination of photothermal and chemodynamic therapy functions of CuS cores with red emitting carbon dots

《化学科学与工程前沿（英文）》 2023年 第17卷 第12期   页码 2144-2155 doi: 10.1007/s11705-023-2362-4

摘要： This study introduces multifunctional silica nanoparticles that exhibit both high photothermal and chemodynamic therapeutic activities, in addition to luminescence. The activity of the silica nanoparticles is derived from their plasmonic properties, which are a result of infusing the silica nanoparticles with multiple Cu2–xS cores. This infusion process is facilitated by a recoating of the silica nanoparticles with a cationic surfactant. The key factors that enable the internal incorporation of the Cu2–xS cores and the external deposition of red-emitting carbon dots are identified. The Cu2–xS cores within the silica nanoparticles exhibit both self-boosting generation of reactive oxygen species and high photothermal conversion efficacy, which are essential for photothermal and chemodynamic activities. The silica nanoparticles’ small size (no more than 70 nm) and high colloidal stability are prerequisites for their cell internalization. The internalization of the red-emitting silica nanoparticles within cells is visualized using fluorescence microscopy techniques. The chemodynamic activity of the silica nanoparticles is associated with their dark cytotoxicity, and the mechanisms of cell death are evaluated using an apoptotic assay. The photothermal activity of the silica nanoparticles is demonstrated by significant cell death under near-infrared (1064 nm) irradiation.

关键词： copper sulfide nanoparticles     chemodynamic therapy     photothermal therapy     carbon dots     silica nanoparticles    

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One-step synthesis of recoverable CuCo

Tongzhou Lu, Yongzheng Zhang, Chun Cheng, Yanbin Wang, Yongming Zhu

《化学科学与工程前沿（英文）》 2020年 第14卷 第4期   页码 595-604 doi: 10.1007/s11705-019-1818-z

摘要： A facile one-step hydrothermal method has been adopted to directly synthesize the CuCo S material on the surface of Ni foam. Due to the relatively large specific surface area and wide pore size distribution, the CuCo S material not only effectively increases the reactive area, but also accommodates more side reaction products to avoid the difficulty of mass transfer. When evaluated as anode for Li-ion batteries, the CuCo S material exhibits excellent electrochemical performance including high discharge capacity, outstanding cyclic stability and good rate performance. At the current density of 200 mA·g , the CuCo S material shows an extremely high initial discharge capacity of 2510 mAh·g , and the cycle numbers of the material even reach 83 times when the discharge capacity is reduced to 500 mAh·g . Furthermore, the discharge capacity can reach 269 mAh·g at a current of 2000 mA·g . More importantly, when the current density comes back to 200 mA·g , the discharge capacity could be recovered to 1436 mAh·g , suggesting an excellent capacity recovery characteristics.

关键词： copper cobalt sulfide     recoverability     one-step hydrothermal method     anode material     Li-ion battery    

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extracellular polymeric substances from activated sludge on the aggregation kinetics of silver and silver sulfide

《环境科学与工程前沿（英文）》 2022年 第16卷 第2期 doi: 10.1007/s11783-021-1450-2

摘要：

• The NPs aggregation in the electrolyte solution is consistent with the DLVO theory.

关键词： Silver nanoparticles     Silver sulfide nanoparticles     Extracellular polymeric substances     Aggregation kinetics     Influence mechanisms    

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Control of hydrogen sulfide emissions using autotrophic denitrification landfill biocovers: engineering

Daoroong SUNGTHONG, Debra R. REINHART

《环境科学与工程前沿（英文）》 2011年 第5卷 第2期   页码 149-158 doi: 10.1007/s11783-011-0324-4

摘要： Hydrogen sulfide (H S) emitted from construction and demolition waste landfills has received increasing attention. Besides its unpleasant odor, long-term exposure to a very low concentration of H S can cause a public health issue. In the case of construction and demolition (C&D) waste landfills, where gas collection systems are not normally required, the generated H S is typically not controlled and the number of treatment processes to control H S emissions in situ is limited. An attractive alternative may be to use chemically or biologically active landfill covers. A few studies using various types of cover materials to attenuate H S emissions demonstrated that H S emissions can be effectively reduced. In this study, therefore, the costs and benefits of H S-control cover systems including compost, soil amended with lime, fine concrete, and autotrophic denitrification were evaluated. Based on a case-study landfill area of 0.04 km , the estimated H S emissions of 80900 kg over the 15-year period and costs of active cover system components (ammonium nitrate fertilizer for autotrophic denitrification cover, lime, fine concrete, and compost), ammonium nitrate fertilizer is the most cost effective, followed by hydrated lime, fine concrete, and yard waste compost. Fine concrete and yard waste compost covers are expensive measures to control H S emissions because of the large amount of materials needed to create a cover. Controlling H S emissions using fine concrete and compost is less expensive at landfills that provide on-site concrete recovery and composting facilities; however, ammonium nitrate fertilizer or hydrated lime would still be more cost effective applications.

关键词： hydrogen sulfide emissions     construction and demolition waste     autotrophic denitrification     landfill biocovers    

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Therapeutic application of hydrogen sulfide donors: the potential and challenges

null

《医学前沿（英文）》 2016年 第10卷 第1期   页码 18-27 doi: 10.1007/s11684-015-0427-6

摘要：

Hydrogen sulfide (H2S), a colorless gas smelling of rotten egg, has long been considered a toxic gas and environment hazard. However, evidences show that H2S plays a great role in many physiological and pathological activities, and it exhibits different effects when applied at various doses. In this review, we summarize the chemistry and biomedical applications of H2S-releasing compounds, including inorganic salts, phosphorodithioate derivatives, derivatives of Allium sativum extracts, derivatives of thioaminoacids, and derivatives of anti-inflammatory drugs.

关键词： hydrogen sulfide     cardiovascular     cancer     hypertension    

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Ozone kinetics of dimethyl sulfide in the presence of water vapor

Haitao WANG

《环境科学与工程前沿（英文）》 2013年 第7卷 第6期   页码 833-835 doi: 10.1007/s11783-013-0570-8

摘要： The outdoor smog chamber was used to thorough investigate the rate constants of gas-phase reaction between dimethyl sulfide (DMS) and ozone (O ) under conditions of relative humidity 55.0%–67.8% at (296±2)K for the first time. The rate constants were measured, at a total pressure of 1 atm, to be (10.4±0.2) × 10 cm ·molecule ·s at relative humidity of 67.5%±0.3% at 298K, (10.1±0.1) × 10 cm ·molecule ·s at relative humidity of 66.5%±0.5% at 296K, (7.75±0.39) × 10 cm ·molecule ·s at relative humidity of 64.8%±0.1% at 294K and (3.42±0.21) × 10 cm ·molecule ·s at relative humidity of 55.8%±0.8% at 295K. Base on these results, it is possible to see the reaction of O /DMS in the presence of water vapor as an important sink for DMS in the earth atmosphere.

关键词： rate constants     ozone (O3)     dimethyl sulfide (DMS)     water vapor    

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Abatement of sulfide generation in sewage by glutaraldehyde supplementation and the impact on the activated

Lehua ZHANG,Jingxing MA,Yinchen JIN,Haiqin ZHANG,Yongdi LIU,Lankun Cai

《环境科学与工程前沿（英文）》 2015年 第9卷 第2期   页码 365-370 doi: 10.1007/s11783-014-0645-1

摘要： Hydrogen sulfide emission in sewer systems is associated with toxicity, corrosion, odour nuisance and high costs treatment. In this study, a novel method to inhibit sulfide generation from sewage by means of glutaraldehyde supplementation has been suggested and evaluated under anaerobic conditions. Different concentrations of glutaraldehyde at 10, 15, 20, 30 and 40 mg·L have been investigated. Besides, the possible impacts of glutaraldehyde supplementation on an activated sludge system and an appraisal of the economic aspects are presented as well. As observed from the experimental results, a dosage of 20 mg·L glutaraldehyde resulted in a significant decrease of the sulfide production by 70%–80% in the simulated sewage. Moreover, the impacts of additional glutaraldehyde at 20 mg·L on activated sludge, in terms of chemical oxygen demand removal and oxygen uptake rates, were negligible. From an economical point of view, the cost of the commercial glutaraldehyde products required in the operation, which was calculated on the basis of activated sulfide removal avoidance, was around €3.7–4.6 S·kg . Therefore it is suggested that glutaraldehyde supplementation is a feasible technique to abate the sulfide problems in sewer systems. Yet further research is required to elucidate the optimum “booster” dosage and the dosing frequency in situ accordingly.

关键词： corrosion     glutaraldehyde     sulfate-reducing bacteria     sulfide     urban sewage    

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New method for efficient control of hydrogen sulfide and methane in gravity sewers: Combination of NaOH

《环境科学与工程前沿（英文）》 2022年 第16卷 第6期 doi: 10.1007/s11783-021-1509-0

摘要：

• The combination of NaOH and nitrite was used to control harmful gas in sewers.

关键词： Sewer corrosion     Sulfide control     Combination treatment     NaOH     Nitrite    

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Copper and zinc interaction on water clearance and tissue metal distribution in the freshwater mussel

Tianxiang XIA, Xuehua LIU

《环境科学与工程前沿（英文）》 2011年 第5卷 第2期   页码 236-242 doi: 10.1007/s11783-010-0218-8

摘要： Copper and zinc interaction on clearance from water and distribution in different tissues was investigated for the freshwater mussel, , under laboratory conditions. Clearance rate of Cu or Zn from water was highly dependent on exposure concentration. Interaction effect was most evident at 300 μg·L Cu exposure and depressed the Zn clearance rate significantly ( <0.05). However, the presence of 100 μg·L and 300 μg·L Zn hardly affected the Cu clearance rate. The 300 μg·L Cu presence enhanced Cu accumulation in each tissue most significantly ( <0.01), but caused Zn content to decrease in the gills by 62% ( <0.05), viscera by 49% ( <0.05) and foot by 31% ( <0.05), and increase in the mantle by 97% ( <0.05) and the muscles by 243% ( <0.05) for different Zn exposure treatments. The response of metal accumulation in various tissues of the test mussels indicated that Zn transferred from the gills, viscera and foot to the mantle and muscles might be one of the important characteristics of the Zn regulatory mechanism by leading to a narrow range of Zn concentration in the different tissues.

关键词： interaction     mussel     copper     zinc     clearance     distribution    

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Identification and assessment of environmental burdens of Chinese copper production from a life cycle

Xiaolong SONG,Jianxin YANG,Bin LU,Bo LI,Guangyuan ZENG

《环境科学与工程前沿（英文）》 2014年 第8卷 第4期   页码 580-588 doi: 10.1007/s11783-013-0599-8

摘要： The environmental burdens of Chinese copper production have been identified and quantified in the context of typical technologies, materials supplies and environmental emissions by a life cycle approach. Primary and secondary copper production using copper ores and scraps, respectively, were analyzed in detail. The flash and bath smelting approaches and the recycling of copper scraps were selected as representative copper production processes. A quantitative analysis was also conducted to assess the influence of material transport distance in copper production. Life cycle assessment (LCA) results showed that resources depletion and human health contribute significantly to environmental burdens in Chinese copper production. In addition, the secondary copper production has dramatically lower environmental burdens than the primary production. There is no obvious distinction in overall environmental burdens in primary copper production by flash or bath smelting approach. However, resources depletion is lower and the damage to human health is higher for flash smelting approach. Ecosystem quality damage is slight for both approaches. Environmental burdens from the mining stage contribute most in all life cycle stages in primary copper production. In secondary copper production, the electrolytic refining stage dominates. Based on the life cycle assessment results, some suggestions for improving environmental performance were proposed to meet the sustainable development of Chinese copper industry.

关键词： copper production     environmental burden     life cycle assessment     refined copper    

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Variability of waste copper slag concrete and its effect on the seismic safety of reinforced concrete

《结构与土木工程前沿（英文）》 2022年 第16卷 第1期   页码 117-130 doi: 10.1007/s11709-021-0788-7

摘要： Proven research output on the behavior of structures made of waste copper slag concrete can improve its utilization in the construction industry and thereby help to develop a sustainable built environment. Although numerous studies on waste copper slag concrete can be found in the published literature, no research has focused on the structural application of this type of concrete. In particular, the variability in the strength properties of waste copper slag concrete, which is required for various structural applications, such as limit state design formulation, reliability-based structural analysis, etc., has so far not attracted the attention of researchers. This paper quantifies the uncertainty associated with the compressive-, flexural- and split tensile strength of hardened concrete with different dosages of waste copper slag as fine aggregate. Best-fit probability distribution models are proposed based on statistical analyses of strength data generated from laboratory experiments. In addition, the paper presents a reliability-based seismic risk assessment of a typical waste copper slag incorporated reinforced concrete framed building, considering the proposed distribution model. The results show that waste copper slag can be safely used for seismic resistant structures as it results in an identical probability of failure and dispersion in the drift demand when compared with a conventional concrete building made of natural sand.

关键词： waste copper slag     quantification of variability     goodness-of-fit test     seismic risk assessment     PSDM    

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Removing carbonyl sulfide with metal-modified activated carbon

Juan QIU,Ping NING,Xueqian WANG,Kai LI,Wei LIU,Wei CHEN,Langlang WANG

《环境科学与工程前沿（英文）》 2016年 第10卷 第1期   页码 11-18 doi: 10.1007/s11783-014-0714-5

摘要： A Cu-Co-K/activated carbon (AC) adsorbent has been developed for the removal of carbonyl sulfide (COS). The effects of COS concentration, reaction temperature and relative humidity were closely examined. A breakthrough of 33.23 mg COS·g adsorbent at 60°C, under 30% relative humidity and in presence of 1.0% oxygen was exhibited in the Cu-Co-K/AC adsorbent prepared. Competitive adsorption studies for COS in the presence of CS , and H S were also conducted. TPD analysis was used to identify sulfur-containing products on the carbon surface, and the results indicated that H S, COS and SO were all evident in the effluent gas generated from the exhausted Cu-Co-K/AC. Structure of the activated carbon samples has been characterized using nitrogen adsorption, and their surface chemical structures were also determined with X-ray photoelectron spectroscopy (XPS). It turns out that the modification with Cu(OH) CO -CoPcS-KOH can significantly improve the COS removal capacity, forming species simultaneously. Regeneration of the spent activated carbon sorbents by thermal desorption has also been explored.

关键词： carbonyl sulfide     activated carbon     removal     reactive adsorption    

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标题 作者 时间 类型 操作

Recent advances of small-molecule fluorescent probes for detecting biological hydrogen sulfide

期刊论文

Structural and optical properties of nanostructured copper sulfide semiconductor synthesized in an industrial

Marcela Achimovičová, Erika Dutková, Erika Tóthová, Zdenka Bujňáková, Jaroslav Briančin, Satoshi Kitazono

期刊论文

迎接铜工业挑战——低成本处理硫化铜精矿途径的思考

朱祖泽

期刊论文

Silica-based nanoarchitecture for an optimal combination of photothermal and chemodynamic therapy functions of CuS cores with red emitting carbon dots

期刊论文

One-step synthesis of recoverable CuCo

Tongzhou Lu, Yongzheng Zhang, Chun Cheng, Yanbin Wang, Yongming Zhu

期刊论文

extracellular polymeric substances from activated sludge on the aggregation kinetics of silver and silver sulfide

期刊论文

Control of hydrogen sulfide emissions using autotrophic denitrification landfill biocovers: engineering

Daoroong SUNGTHONG, Debra R. REINHART

期刊论文

Therapeutic application of hydrogen sulfide donors: the potential and challenges

null

期刊论文

Ozone kinetics of dimethyl sulfide in the presence of water vapor

Haitao WANG

期刊论文

Abatement of sulfide generation in sewage by glutaraldehyde supplementation and the impact on the activated

Lehua ZHANG,Jingxing MA,Yinchen JIN,Haiqin ZHANG,Yongdi LIU,Lankun Cai

期刊论文

New method for efficient control of hydrogen sulfide and methane in gravity sewers: Combination of NaOH

期刊论文

Copper and zinc interaction on water clearance and tissue metal distribution in the freshwater mussel

Tianxiang XIA, Xuehua LIU

期刊论文

Identification and assessment of environmental burdens of Chinese copper production from a life cycle

Xiaolong SONG,Jianxin YANG,Bin LU,Bo LI,Guangyuan ZENG

期刊论文

Variability of waste copper slag concrete and its effect on the seismic safety of reinforced concrete

期刊论文

Removing carbonyl sulfide with metal-modified activated carbon

Juan QIU,Ping NING,Xueqian WANG,Kai LI,Wei LIU,Wei CHEN,Langlang WANG

期刊论文